HEAT TRANSFER
The thermal conductivity of titanium is roughly 50% higher than 316 stainless steel as shown
in Table 8. This contributes to its excellent heat transfer
properties.
The overall heat transfer coefficient, U (Btu/hr./ft.squared/degrees F),
indicates the ability of a surface to transfer heat from one flowing fluid on one side to
another fluid on the opposite side. The inverse of the coefficient, (1/U), can be considered
to be the total resistance to heat flow which, as indicated in Figure 3,
is made up of five component resistances: tube-side fluid, rt, tube-side fouling, rtf, tube
metal, rm, shell-side fouling, rsf, and shell-side fluid, rs. An ideal tube material will
resist fouling (minimizing rtf and rsf), permit high tube side velocities (minimizing rt),
and be usable in thinnest section (minimizing rm).
A zero corrosion allowance can often be specified for titanium. This, coupled with adequate
strength, permits titanium tubing to be used with unusually thin walls.
The high resistance of titanium to corrosion prevents buildup of corrosion products which rob other
metals of heat transfer efficiency. Titanium's hard, smooth surface also minimizes buildup of external
fouling films and makes cleaning and maintenance easier. The smooth surface on titanium is also
thought to promote dropwise condensation. The result, as shown in Figure 4, is high rates of
distillation and condensation for titanium, compared to other metals.
The excellent resistance of titanium to turbulence and erosion- corrosion permits use of relatively
high flow rates of 18-22 ft./sec. in silt-laden seawater or even up to 100 ft./sec. in clean seawater
without damage to the passive oxide film. Tests in 80 degree F. sea water for 60 days at 25 ft./sec.
have shown titanium's corrosion-erosion
resistance to be 80 times better than that of the next-best material, a copper-nickel alloy.
Other tests in 85 degrees F. sea water for 60 days at 27 ft./sec. proved titanium to be
almost 100 times better than stainless steel, the next-best material.
Putting it all
together--the resulting overall heat transfer rate of titanium surfaces is often comparable
to that of metals with higher thermal conductivity. The data in Figure 5,
for instance, illustrate that the overall heat transfer coefficient of titanium in a
desalination environment equaled that of 90-10 copper nickel after a short operating period.
The copper-nickel alloy, due to its higher thermal conductivity, had a higher overall heat
transfer coefficient when first placed in service with clean surfaces. However, as fouling
due to corrosion product proceeded on the 90-10 alloy with time, the heat transfer
coefficient dropped to a value equal to that of titanium which did not experience corrosion
product fouling. In these tests, sea water moved at 5 ft./sec. inside 3/4" x 19 gage
tubes and steam was condensing on the outside. Had thin-walled titanium tubing been used as
is present practice, the heat transfer coefficient for titanium would have been higher than
that of the copper-nickel alloy almost from the start.